Carbon Materials & Graphite

Carbon Materials & Graphite — Structure, Order, and Potential

Carbon materials are not defined by their elemental composition.
They are defined by
structure—how carbon atoms organize themselves across length scales, from nanometric domains to macroscopic morphology.
This organisation determines conductivity, mechanical behaviour, reactivity, surface chemistry, and ultimately
performance in industrial applications.

Microscopy and spectroscopy reveal the trajectory of carbon, not merely its current state.

Natural precursors are not equal

Anthracite, semi-graphite, and graphite may share carbon percentages, yet they are not interchangeable.
Their microstructure retains memories of:

  • precursor biological architecture (vitrinite, inertinite, liptinite)

  • tectonic strain and compaction

  • devolatilisation pathways

  • fluid interaction

  • catalytic vs non-catalytic graphitisation

  • weathering and oxidation

These histories manifest as distinct domain size distributions, stacking order, and turbostratic defects, which control how a material responds to heat, pressure, or electrochemical cycling.

Natural Graphite. Canada. Photomicrograph taken with reflected white light and lambda plate.

Natural Graphite. Canada. Photomicrograph taken with reflected white light and lambda plate.

Graphitisation is a process, not a label

The term “graphite” is often applied loosely.
At the microscopic scale, most “graphite” encountered in natural or synthetic contexts is turbostratic carbon: layered but rotationally disordered.

True graphitisation requires:

  • lateral domain growth

  • basal plane alignment

  • decrease in defect density

  • reduction of heteroatom interference

  • collapse of cross-linking residuals

Raman and XRD do not simply “identify graphite”— they quantify how close a material is to acting like one.

Synthetic graphite. Photomicrograph taken with reflected white light and lambda plate.

Synthetic graphite. Photomicrograph taken with reflected white light and lambda plate.

What CarbonMat evaluates

We characterise structure using a complementary set of methods:

  • Raman spectroscopy: disorder, crystallite size (La, Lc), band ratios and widths

  • XRD: interlayer spacing (d₀₀₂), stacking order, graphitic vs turbostratic indices

  • Optical microscopy: inherited textures, precursor macerals, carbonisation pathways

  • SEM/EDS (where relevant): porosity, morphology, mineral residues

These datasets are integrated—not treated as isolated metrics—to determine the trajectory of your material, not merely its label.

Natural semigraphite. Kaiserberg, Germany. Photomicrograph taken with reflected white light and lambda plate.

Natural semigraphite. Kaiserberg, Austria. Photomicrograph taken with reflected white light and lambda plate.

Why interpretation matters

Two samples with identical carbon >90% cannot be assumed to behave the same way.
Their microstructural inheritance controls:

  • thermal conversion routes

  • suitability as anode precursor

  • catalytic response during graphitisation

  • oxidation resistance

  • mechanical integrity in composites

  • propensity to produce CNT/CNF during processing

  • success or failure in scale-up

Bulk chemistry will not warn you of failure. Microstructure will.

Char from coal. Photomicrograph taken with reflected white light and lambda plate.

Char from coal. Photomicrograph taken with reflected white light and lambda plate.

Applications we support

  • Anode material development

  • Alternative carbon precursors for battery technologies

  • Electrode performance optimisation

  • High-temperature carbon products (furnaces, refractories, crucibles)

  • Research and pilot plant programs

  • Academic collaborations

You receive:

  • quantitative datasets

  • microstructural interpretation

  • implications for processing route selection

Work with CarbonMat

Tell us:

  • what material you have,

  • what you want it to become,

  • the constraints of your process.

CarbonMat will determine the most effective analytical pathway to evaluate its potential.

High temparature treatment (2500°C) of a meta-anthracite from Douro Basin, Portugal. Photomicrograph taken with reflected white light and lambda plate.

High temparature treatment (2500°C) of a meta-anthracite from Douro Basin, Portugal. Photomicrograph taken with reflected white light and lambda plate.

Natural materials as high-value precursors

Coal-derived carbons, anthracite, semi-coke, and pyrolytic products are increasingly strategic.
Their advantage lies not in purity, but in pre-existing structural ordering that industrial synthesis cannot easily replicate.

Understanding these architectures is the difference between:

  • a precursor that graphitises at 2700°C
    and

  • one that graphitises at 3100°C, or not at all.

CarbonMat assesses why.

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